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I will only give the answer in terms of self-defense against a charging Cape Buffalo Official Thank you Undertaker 1984-2020 shirt by tshirtat store. This assumes there is no option but to shoot as the animal is in a full charge, that you are armed with a .375 H&H or larger, and that there is no good tree next to you to climb. Shooting it through the heart in a full charge will not necessarily stop it in time. I have seen a buffalo run 80 meters after being shot through the heart. Unfortunately for us, they had moved into Jess Bush, a type of very thick thorny vegetation. It is a common tactic for injured buffalos to take refuge in dense bush and it is extremely dangerous to pursue them in such areas as they are extremely aggressive, have acute senses, are very cunning and it is almost impossible to move quietly through Jess.
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However, it was our job and we had no choice but to go after them so in we went Official Thank you Undertaker 1984-2020 shirt by tshirtat store. The first one came flying at us through Jess and came out into a small clearing about twenty meters from me. It dropped its head to hit me at about fifteen meters at which point I shot it. We found the second one about 5 hours later in a much bigger clearing. He was on the other side of a small valley, about 80 meters away. This is far to shoot with a heavy caliber rifle and open sights and normally would not be done because of the chance of wounding. I gave the go-ahead to Jesse to shoot though because the animal was already injured, dangerous to the local population, and surrounded by Jess bush, where it would be more difficult and dangerous to find him.